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Significance of organic co-solvent Ethylene Glycol on Thermodynamic Parameters of hydrolysis of Benzyl Methanoate Catalysed by an acid
Author Name : Rameshwar Dubey
ABSTRACT
The study of organic hydrolysis of Benzyl methanoate was carried out in water EG (Ethylene Glycol) media in which the composition of the organic co-solvent was varying concentration from 30% to 80% (v/v) ranging from 293K to 313K. And it gives an idea about acidic hydrolysis of Benzyl methanoate ester with the help of enthalpy of activation H*, entropy of activation S* and Gibbs free energy of activation G*.
The cause for decline in the values of Specific rate constants, the small increase in G* Values and regular decrease in the values of H* and S* have been mentioned below.